Executive SummaryThis report presents an analysis of the thermal stability of the contents of the settler tanks during planned grouting through the subsequent handling and packaging operations for disposition of the settler tanks to the Environmental Restoration Disposal Facility (ERDF).
BackgroundTen 16-foot-long and 20-inch diameter horizontal tanks currently reside in a stacked 2×5 (high) array in the ~20,000-gallon water-filled Weasel Pit of the 105-KW Fuel Storage Basin on the US-DOE Hanford Site. These ten tanks are part of the Integrated Water Treatment System used to manage water quality in the KW Basin and are called "settler" tanks because of their application in removing particles from the KW Basin waters. Based on process knowledge, the settler tanks are estimated to contain about 124 kilograms of finely divided uranium metal, 22 kg of uranium dioxide, and another 55 kg of other radioactive sludge. The Sludge Treatment Project (STP), managed by CH2MHill Plateau Remediation Company (CHPRC) is charged with managing the settler tanks and arranging for their ultimate disposal by burial in ERDF.PNNL-24200 53451-RPT21, Rev. 0 v laboratory testing at PNNL and elsewhere, which show that grouting has practically no impact on the rates of uranium metal corrosion compared with the rates in water alone, are summarized. Prior Hanford Site process experience in grouting uranium metal chips and fines from fuel fabrication operations also is described.The general composition of the K East Discharge Chute grout, which includes Portland Type I/II cement, Class F fly ash, and water (as well as rheological modifiers and anti-washout additives), is examined as an appropriate formulation for use in the settler tanks based on its previous use and the commonality of data quality objectives established for its development (i.e., good flow properties, low heat generation rate, sufficient set strength to allow its size-reduction without undue crumbing). The thermodynamics and kinetics of Portland cement and fly ash hydration reactions (setting or curing) then are examined to help forecast heat generation rates as functions of reaction temperature and time.With inputs established for geometry (settler tanks, uranium metal particle size and depth, and waste box dimensions), heat sources (e.g., uranium metal reaction and decay heat, grout hydration, and solar heating), and physical properties, heat transport finite element analyses were applied to evaluate the thermal stability of various process steps associated with the solidification and subsequent handling of the settler tank material. For the modeling assessment, thermal instability was defined/declared when the temperature in the uranium-rich sludge bed exceeded 100 °C. At this temperature, water vapor voids form in the sludge, drastically diminishing thermal conductivity, while uranium metal reaction with water continues unabated, thus engendering thermal runaway conditions. Key observations and recommendations from the modeling are summarized below.Underwater grouting of t...