Abstract:The frequencies of the optically active lattice vibrations of carbon monoxide in the low temperature phase are calculated. The crystal structure is reported to be cubic with space group symmetry Pa3 and with four molecules per unit cell. The infrared spectrum of solid carbon monoxide at 20 °K (2000—3000 cm-1) given by Ewing and Pimentel is used. The molecular crystal is considered as an ensemble of harmonic oscillators, and the FG-matrix method of Wilson is applied. With the help of the F- and G-Matrices of a … Show more
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