Benzoxaborolate ligands in group 13 metal complexes

Jaśkowska, Eliza; Justyniak, Iwona; Cyrański, Michał K.; Adamczyk‐Woźniak, Agnieszka; Sporzyński, Andrzej; Zygadło‐Monikowska, Ewa; Ziemkowska, Wanda

doi:10.1016/j.jorganchem.2013.01.023

Cited by 13 publications

(4 citation statements)

References 41 publications

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“…The molecular structure of the aluminum–benzoxaborole complex 455 (Scheme ) has been reported by Ma et al Other complexes of benzoxaborole 1 with group 13 metalsaluminum ( 456 ), gallium ( 457 , 458 ), and indium ( 459 )have been recently obtained and their molecular and crystal structures measured by XRD . Magnesium and calcium complexes of 1 have been also prepared …”

Section: Applicationsmentioning

confidence: 80%

Recent Developments in the Chemistry and Biological Applications of Benzoxaboroles

2015

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Section: Applicationsmentioning

confidence: 80%

Recent Developments in the Chemistry and Biological Applications of Benzoxaboroles

2015

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“…Interestingly, in the case of the Ca phase, a deprotonated anion was also observed (Figure 8, dashed orange line). Forming such a deprotonated species was somewhat unexpected given that reactions had been carried out in water, and that so far deprotonated benzoxaborolates had only been observed when working in anhydrous conditions [28]. It is interesting to notice that in this Ca-benzoxaborolate structure, in which both planar and tetrahedral benzoxaborolate anions are present [27], the Ca .…”

Section: Solid State Nmrmentioning

confidence: 95%

Coordination Networks Based on Boronate and Benzoxaborolate Ligands

et al. 2016

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Abstract:Despite the extensive range of investigations on boronic acids (R-B(OH) 2 ), some aspects of their reactivity still need to be explored. This is the case for the coordination chemistry of boronate anions (R-B(OH) 3´) , which has only recently been started to be studied. The purpose of this review is to summarize some of the key features of boronate ligands (and of their cyclic derivatives, benzoxaborolates) in materials: (i) coordination properties; (ii) spectroscopic signatures; and (iii) emerging applications.

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“…A benzoxaborole reagent was condensed with various group 13 metal trialkyls to form a series of group 13 metal benzoxaborolate dimers (437−439) with planar M 2 O 2 cores (eq 17). 286 Table 4 lists examples of small inorganic heterocycles [R 2 M(μ-ER′)] 2 containing Ga and In in tandem with intraring-positioned group 16 elements (S, Se, and Te). The (449), respectively.…”

Section: Group 13 Rings Containing Boronmentioning

confidence: 99%

“…A benzoxaborole reagent was condensed with various group 13 metal trialkyls to form a series of group 13 metal benzoxaborolate dimers ( 437 – 439 ) with planar M 2 O 2 cores (eq ) …”

Section: Inorganic Rings Derived From Group 12–17 Elementsmentioning

confidence: 99%