Abstract:Based on benzo[i]dipyrido[3,2-a:2′,3′-c]phenazine (dppn) with photo-oxidation activity, complexes [Ir(pbt) 2 (dppn)] Cl (1) and [Ir(pt) 2 (dppn)]Cl (2) have been synthesized (pbtH = 2-phenylbenzothiazole, and ptH = 2-phenylthiazole), with two aims, including studying the influence of the cyclometalating ligands (pbt − in 1, pt − in 2) on the photo-oxidation activity of these complexes and exploring their photo-oxidation-induced luminescence. Both 1 H nuclear magnetic resonance (NMR) and electrospray (ES) mass … Show more
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.