“…The S16‐N22, S16‐O19, S16‐O20 and C13‐S16 bond lengths were obtained at 1.610 (2)/1.672 Å, 1.442 (18)/1.444 Å, 1.435 (18)/1.444 Å and 1.764 (3)/1.795 Å (exp./cal.) in our study, while these bond lengths for 4‐X–C 6 H 4 SO 2 NH 2 (X=CH 3 , NH 2 , H, F, Cl and Br) compounds in the literature were found as 1.610 (6) Å, 1.610 Å, 1.597 (8) Å, 1.601 (2) Å, 1.595 (18) Å and 1.599 (3) Å for S16‐N22 bond length, 1.433 (5) Å, 1.470 Å, 1.408 (9) Å, 1.437 (14) Å, 1.430 (14) Å and 1.432 (2) Å for S16‐O19 one, 1.428 (5) Å, 1.410 Å, 1.394 (8) Å, 1.431 (14) Å, 1.430 (14) Å and 1.426 (3) Å for S16‐O20 one, 1.788 (8) Å, 1.740 Å, 1.755 (9) Å, 1.763 (2) Å, 1.767 (18) Å and 1.768 (3) Å for C13‐S16 one, respectively . In our study, we obtained 107.65 (12)°/107.19° for C13‐S16‐N22 bond angle and 117.22 (11)°/122.94° for O19‐S16‐O20 one.…”