Benzene-1,4-Di(dithiocarboxylate) Linker-Based Coordination Polymers of Mn2+, Zn2+, and Mixed-Valence Fe2+/3+
Margit Aust,
Marina I. Schönherr,
Dominik P. Halter
et al.
Abstract:Three new coordination polymers (CPs) constructed from the linker 1,4-di(dithiocarboxylate) (BDDTC 2− )� the sulfur-analog of 1,4-benzenedicarboxylate (BDC 2− )�together with Mn-, Zn-, and Fe-based inorganic SBUs are reported with description of their structural and electronic properties. Singlecrystal X-ray diffraction revealed structural diversity ranging from one-dimensional chains in [Mn(BDDTC)(DMF) 2 ] (1) to twodimensional (2D) honeycomb sheets observed for [Zn 2 (BDDTC) 3 ][Zn(DMF) 5 (H 2 O)] (2). Gas a… Show more
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