Beiträge zur molekular‐statistischen Thermodynamik

Svenson, Erik

doi:10.1002/andp.19283921906

Annalen der Physik

1928

DOI: 10.1002/andp.19283921906

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Beiträge zur molekular‐statistischen Thermodynamik

Erik Svenson¹

Abstract: 1) ,,Molekular-statistische Thermodynamik vom klassischen Standpunkt aus", erschienen in den Abhandlungen des Herderinstitutes in Riga Bd. 3. 1928. -Weiterhin zitiert unter ,,Stat. Tlierm." 2) A. Smekal, Handb. d. Phys., herausgeg.

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1937

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Internal Volume and the Entropy of Vaporization of Liquids

Rice

1937

The Journal of Chemical Physics

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An effective internal volume, Ve, of a liquid is defined by the equation ΔS = R ln Vv/Ve, where ΔS = entropy of vaporization, and Vv = molal volume of the vapor in equilibrium. A condition for equilibrium is found which gives ΔS in terms of Ve/V and dVe/dV, where V is the actual molal volume of the liquid. The experimental data are considered in the light of this relationship, and the reason for the approximate validity of Trouton's or Hildebrand's rule is discussed. The nature of the relation between the internal and actual volume and its connection with the specific heat of the liquid is considered. Finally suggestions are made in way of explanation of the fact that entropies of vaporization of associated liquids are practically invariably high.

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Internal Volume and the Entropy of Vaporization of Liquids

Rice

1937

The Journal of Chemical Physics

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Beiträge zur molekular‐statistischen Thermodynamik

Abstract: 1) ,,Molekular-statistische Thermodynamik vom klassischen Standpunkt aus", erschienen in den Abhandlungen des Herderinstitutes in Riga Bd. 3. 1928. -Weiterhin zitiert unter ,,Stat. Tlierm." 2) A. Smekal, Handb. d. Phys., herausgeg.

Cited by 1 publication

References 4 publications

Internal Volume and the Entropy of Vaporization of Liquids

Internal Volume and the Entropy of Vaporization of Liquids

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