Beitrag zur reaktionskinetischen Simultananalyse

Analysis of Mixtures of Hydroxyl Compounds Using Differential Reaction Rates.

“…However, the equations worked out by Schmalz and Geiseler (10) provide a convenient means of calculating the composition of ternary mixtures if all of the components react with a common reagent.…”

“…Modern analytical methods and separation techniques are making it possible to better understand the chemistry of the nonbasic nitrogen compounds in petroleum. The definition of nonbasic nitrogen compounds proposed by Richter and coworkers (10) as those nitrogen compounds having a pA'a g 2 is used in this paper.…”

Synergistic Effects in Analyses Based on Differential Reaction Rates.

“…For the analysis of mixtures, the wide applicability of the graphical method based on rates of reaction has been demonstrated (1)(2)(3)(4)(5)(6)(7)(8)(8)(9)(10)(11). When using this method for binary mixtures, it was noted that in some cases the slope of the second portion of the rate plots, the linear portion which represents the rate of reaction of the slower component after essentially all the faster component has reacted, deviated significantly from the slope of the rate plot when the same material reacted alone, using the same initial concentra-tion of reactants, a and 6 (8).…”

“…The data for construction of the second-order theoretical curves were calculated by the method of Schmalz and Geiseler (7).…”