Beitrag zur Kenntnis der Reaktionsfähigkeit höherer Alkylhalogenide

Overcrowding factors of mosquito larvae. 10. Structure-activity relationship of 3-methylalkanoic acids and their esters against mosquito larvae

“…The 2-alkanols synthesized and their melting points and boiling points are as follows: 2-tridecanol, bp 115-116 °C (0.2 mm); 2-tetradecanol, bp 120-122 °C (0.2 mm); 2pentadecanol, bp 124-126 °C (0.2 mm); 2-hexadecanol, bp 129-132 °C (0.2 mm) [lit. bp 135 °C (1 mm); Asinger and Eckoldt, 1943], mp 42-43 °C (lit. mp 42.2-45 °C; Breusch and Sokullu, 1953); 2-heptadecanol, bp 135-138 °C (0.2 mm), mp 46-47 °C (lit.…”

Structure and Reactivity. I. The Oximation Rates of Some Straight-Chain and Monomethyl-Substituted Alkanones

“…In both series the rate becomes constant with the third and second member, respectively. The n-propyl and higher ketones (17)(18)(19)(20)(21)(22)(23)(24)(25)(26)(27) have the same rate. The above order of reactivity holds true for all of the branched homologous series shown in Table I, the isopropyl ketones (28-34) serving as an example.…”