2014
DOI: 10.1021/ef402455h
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Bed Agglomeration Characteristics during Cocombustion of Animal Waste with Municipal Solid Waste in a Bubbling Fluidized-Bed Boiler—A Thermodynamic Modeling Approach

Abstract: Full-scale waste combustion tests showed that adding animal waste (AW) to municipal solid waste (MSW) prevented bed agglomeration, and the reason for this finding was not fully understood. This study uses thermodynamic modeling to investigate the composition of equilibrium products for two combustion scenarios: monocombustion of MSW (the reference case) and cocombustion of AW with MSW (the AW case). The modeling was performed using FactSage, and experimental data obtained during the full-scale combustion tests… Show more

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Cited by 5 publications
(5 citation statements)
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“…Thermodynamic equilibrium modeling, coupled with experimental methods, has been used to achieve a better understanding of the ash transformation mechanisms during the combustion of biomass and waste-derived fuels. 7−12 In a previous study, 13 a thermodynamic equilibrium model was applied to assess the composition of the bottom ash in a commercial bubbling fluidized-bed (BFB) boiler, combusting a waste mixture of 20% MSW and 80% IW, referred herein as Solid Waste (SW). Data obtained from the full-scale tests were used as input for the equilibrium model, to evaluate the agglomeration tendency based on the different fuel composition, bed temperature, and air/fuel ratio.…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…Thermodynamic equilibrium modeling, coupled with experimental methods, has been used to achieve a better understanding of the ash transformation mechanisms during the combustion of biomass and waste-derived fuels. 7−12 In a previous study, 13 a thermodynamic equilibrium model was applied to assess the composition of the bottom ash in a commercial bubbling fluidized-bed (BFB) boiler, combusting a waste mixture of 20% MSW and 80% IW, referred herein as Solid Waste (SW). Data obtained from the full-scale tests were used as input for the equilibrium model, to evaluate the agglomeration tendency based on the different fuel composition, bed temperature, and air/fuel ratio.…”
Section: Introductionmentioning
confidence: 99%
“…In a previous study, a thermodynamic equilibrium model was applied to assess the composition of the bottom ash in a commercial bubbling fluidized-bed (BFB) boiler, combusting a waste mixture of 20% MSW and 80% IW, referred herein as Solid Waste (SW). Data obtained from the full-scale tests were used as input for the equilibrium model, to evaluate the agglomeration tendency based on the different fuel composition, bed temperature, and air/fuel ratio.…”
Section: Introductionmentioning
confidence: 99%
“…The fuel fingerprint allowed for quickly investigating how various fuel blends would affect the overall inorganic composition when deciding what blends that would be suitable. The approach with thermodynamical equilibrium calculations, which have been used previously for phosphorus-rich biomass, 16 proved a valuable tool for evaluating the fuel blends prior to actual experiments, and it worked well enough for the fuel system investigated here. The ash composition in this case, dominated by calcium, silicon, moderate amounts of phosphorus together with a very low alkali content, lends itself well to this type of slag modelling using current databases, which may not be the case for all types of fuel blends.…”
Section: Discussionmentioning
confidence: 99%
“…The ash-induced problems have a significant impact on the operation of fluidized beds; hence, even qualitative predictions are essential. The proposed modeling approaches are usually based on equilibrium phase calculations for predicting what thermodynamically stable phases can form from reactions between the ash and bed material . The thermodynamic calculations can be further expanded by adding a diffusion model or even modeling the particle coating using discrete element models .…”
Section: Influence Of Fluidized Bed On Combustionmentioning
confidence: 99%
“…The proposed modeling approaches are usually based on equilibrium phase calculations for predicting what thermodynamically stable phases can form from reactions between the ash and bed material. 247 The thermodynamic calculations can be further expanded by adding a diffusion model 243 or even modeling the particle coating using discrete element models. 248 Alternatively, predictions can be based on empirical correlations.…”
Section: Influence Of Fluidized Bed On Combustionmentioning
confidence: 99%