Batteries: Progress in Rechargeable Aqueous Zinc‐ and Aluminum‐Ion Battery Electrodes: Challenges and Outlook (Adv. Sustainable Syst. 1/2019)

Verma, Vivek; Kumar, Sonal; Manalastas, William; Satish, Rohit; Srinivasan, Madhavi

doi:10.1002/adsu.201970004

Cited by 30 publications

(33 citation statements)

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“…PBA materials have also been regarded as promising hosts for reversible insertion/extraction of multivalent ions (e.g., Zn 2+ , [ 49 ] Mg 2+ , [ 38 ] Ca 2+ , [ 122 ] Al 3+[ 123,124 ] ), due to their 3D open framework with large interstitial sites for fast reaction kinetics. The robust 3D frameworks of PBAs are stable toward the insertion/extraction of various multivalent ions, and the correlated applications in various kind of batteries could be illustrated as follows:…”

Section: Prospects On Future Research and Development Of Pba Cathode mentioning

confidence: 99%

Structure and Properties of Prussian Blue Analogues in Energy Storage and Conversion Applications

Qin

Shihua

et al. 2020

Adv Funct Materials

288

209

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In recent years, Prussian blue analogue (PBA) materials have been widely explored and investigated in energy storage/conversion fields. Herein, the structure/property correlations of PBA materials as host frameworks for various charge‐carrier ions (e.g., Na+, K+, Zn2+, Mg2+, Ca2+, and Al3+) is reviewed, and the optimization strategies to achieve advanced performance of PBA electrodes are highlighted. Prospects for further applications of PBA materials in proton, ammonium‐ion, and multivalent‐ion batteries are summarized, with extra attention given to the selection of anode materials and electrolytes for practical implementation. This work provides a comprehensive understanding of PBA materials, and will serve as a guidance for future research and development of PBA electrodes.

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Section: Prospects On Future Research and Development Of Pba Cathode mentioning

confidence: 99%

Structure and Properties of Prussian Blue Analogues in Energy Storage and Conversion Applications

Qin

Shihua

et al. 2020

Adv Funct Materials

288

209

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“…Recently, Zn-ion batteries have won a lot of attention [15]. Among the cathode materials, many vanadium-based oxides have been reported such as Zn 0.25 V 2 O 5 ·2H 2 O [16], Fe 5 V 15 O 39 (OH) 9 ·9H 2 O [17], Zn 3 V 2 O 7 (OH) 2 ·2H 2 O [6], H 2 V 3 O 8 [18], LiV 3 O 8 [19], and Na 2 V 6 O 16 ·1.63H 2 O nanoribbon [20].…”

Section: Introductionmentioning

confidence: 99%

Ultrafast Synthesis of Calcium Vanadate for Superior Aqueous Calcium-Ion Battery

Liu

Rozier

et al. 2019

Research

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Recently, multivalent aqueous calcium-ion batteries (CIBs) have attracted considerable attention as a possible alternative to Li-ion batteries. However, traditional Ca-ion storage materials show either limited rate capabilities and poor cycle life or insufficient specific capacity. Here, we tackle these limitations by exploring materials having a large interlayer distance to achieve decent specific capacities and one-dimensional architecture with adequate Ca-ion passages that enable rapid reversible (de)intercalation processes. In this work, we report the high-yield, rapid, and low-cost synthesis of 1D metal oxides MV3O8 (M=Li, K), CaV2O6, and CaV6O16·7H2O (CVO) via a molten salt method. Firstly, using 1D CVO as electrode materials, we show high capacity 205 mA h g-1, long cycle life (>97% capacity retention after 200 cycles at 3.0 C), and high-rate performance (117 mA h g-1 at 12 C) for Ca-ion (de)intercalation. This work represents a step forward for the development of the molten salt method to synthesize nanomaterials and to help pave the way for the future growth of Ca-ion batteries.

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“…Aluminum (Al) has also been considered as an attractive candidate for the aqueous metal batteries because of its inherent properties, [ 53–58 ] including the most abundant metal in the earth crust, high theoretical energy capacity, low molecular mass, as well as the negative standard electrode potential of −1.76 V versus SHE. According to the Pourbaix diagram of Al‐water system (Figure 2b), the formation of Al 3+ ion dominates upon discharge based on the following process

Acid solution : Al \to {Al}^{3 +} + 3 e^{-}

…”

Section: Fundamental Backgrounds Of Armbsmentioning

confidence: 99%

Stabilization Perspective on Metal Anodes for Aqueous Batteries

Wang

Tan

Yang

et al. 2020

Advanced Energy Materials

125

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Aqueous electrolyte‐based batteries have attracted increasing attention because of nonflammability, low cost, high power density, and environmental friendliness. However, the low energy density of aqueous lithium‐ion batteries caused by the narrow stable electrochemical window of water and electrode materials with low capacity severely limits their further development. In this regard, the development of metal anodes with high specific capacity shows excellent prospects. For example, metal zinc and aluminum anodes have high theoretical specific capacity, rich resources, and environmental friendliness, and can be used as promising anodes for high‐energy‐density aqueous rechargeable metal batteries. Unfortunately, metal anodes usually face balance issues with regard to stability and activity associated with dendrite growth and undesired side reactions in water‐based electrolytes, which is still a great challenge for aqueous metal batteries. In this review, various aqueous metal batteries including aqueous rechargeable metal batteries and aqueous metal–air batteries are summarized and highlighted. Recent advances in the design of high‐safety aqueous electrolytes and the strategies for metal anode protection are comprehensively reviewed. In addition, emerging challenges and some perspectives on the development of high‐energy‐density aqueous metal batteries are included.

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Batteries: Progress in Rechargeable Aqueous Zinc‐ and Aluminum‐Ion Battery Electrodes: Challenges and Outlook (Adv. Sustainable Syst. 1/2019)

Cited by 30 publications

References 0 publications

Structure and Properties of Prussian Blue Analogues in Energy Storage and Conversion Applications

Structure and Properties of Prussian Blue Analogues in Energy Storage and Conversion Applications

Ultrafast Synthesis of Calcium Vanadate for Superior Aqueous Calcium-Ion Battery

Stabilization Perspective on Metal Anodes for Aqueous Batteries

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