2017
DOI: 10.1007/s11696-016-0124-1
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Batch synthesis of polyoxometalate-based phosphonium compounds by one-step room-temperature mechanochemical process, and their morphology-dependent antibacterial activities

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Cited by 12 publications
(6 citation statements)
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“…Additionally, it is clear that cationic biocides kill bacteria by binding to negatively charged cell surface and disrupting the cell membranes, in which different charge distributions and alkyl chain length play a key role in the antibacterial efficacy. 46,59 In this study, three phosphonium-based ILs with different long alkyl chains (C 12 and C 14 ) exhibit antifungal activity, which is consistent with previous reports indicating that phosphonium compounds containing a long alkyl chain (C 8 -C 18 ) usually exert antimicrobial capabilities. 45,60,61 Regarding the [P 44412 ][POM] with a shorter alkyl chain, a high level of antifungal activity is observed, which may be affected by many potential important factors, such as hydrophobic-hydrophilic balance, 62,63 adsorption, and critical micelle concentration.…”
Section: The Antifungal Activities Of [P 44412 ][Pom] [P 44414 ][Pom] and [P 66614 ]supporting
confidence: 91%
“…Additionally, it is clear that cationic biocides kill bacteria by binding to negatively charged cell surface and disrupting the cell membranes, in which different charge distributions and alkyl chain length play a key role in the antibacterial efficacy. 46,59 In this study, three phosphonium-based ILs with different long alkyl chains (C 12 and C 14 ) exhibit antifungal activity, which is consistent with previous reports indicating that phosphonium compounds containing a long alkyl chain (C 8 -C 18 ) usually exert antimicrobial capabilities. 45,60,61 Regarding the [P 44412 ][POM] with a shorter alkyl chain, a high level of antifungal activity is observed, which may be affected by many potential important factors, such as hydrophobic-hydrophilic balance, 62,63 adsorption, and critical micelle concentration.…”
Section: The Antifungal Activities Of [P 44412 ][Pom] [P 44414 ][Pom] and [P 66614 ]supporting
confidence: 91%
“…Very recently, a series of compounds composed of POM and phosphonium groups (MePh 3 P) showed also antibacterial activity against both Staphylococcus aureus and Escherichia coli , which was even stronger than that of the antibiotic ampicillin as judged by the size of the inhibitory zones on agar plates. 89 The (MePh 3 P) n –POM systems ( n = 3 or 4) are based on the Keggin-type POMs [SiW 12 O 40 ] 4– , [PW 12 O 40 ] 3– or [PMo 12 O 40 ] 3– and the quaternary phosphonium salt methyl triphenyl phosphonium iodide (MePhPI). It was described that the antibacterial activity increased with increasing content of crystal water within the structures.…”
Section: Antibacterial Activity Of Pom-based Nanocompositesmentioning
confidence: 99%
“…62,69 The confidence level of results is as follows: *p < 0.05, **p < 0.005, ***p < 0.001, and ****p < 0.00001. This assumption is supported by Hu et al, 54 who demonstrated that a concentration of [PW 12 O 40 ] 3− as high as 1000 ppm did not inhibite the growth of S. aureus or E. coli. We found that this is also true for a fungal species.…”
Section: Resultsmentioning
confidence: 69%