The spectral energy distribution of blazars around the synchrotron peak can be well described by the logparabolic model that has three parameters: peak energy (E p ), peak luminosity (L p ) and the curvature parameter (b). It has been suggested that E p shows relations with L p and b in several sources, which can be used to constrain the physical properties of the emitting region and/or acceleration processes of the emitting particles. We systematically study the E p -L p and E p -(1/b) relations for 14 BL Lac objects using the 3-25 keV RXTE/PCA and 0.3-10 keV Swift/XRT data. Most objects (9/14) exhibit positive E p -L p correlations, three sources show no correlation, and two sources display negative correlations. In addition, most targets (7/14) present no correlation between E p and 1/b, five sources pose negative correlations, and two sources demonstrate positive correlations. 1ES 1959+650 displays two different E p -L p relations in 2002 and 2016. We also analyze E p -L p and E p -(1/b) relations during flares lasting for several days. The E p -L p relation does not exhibit significant differences between flares, while the E p -(1/b) relation varies from flare to flare. For the total sample, when L p < 10 45 erg s -1 , there seems to be a positive E p -L p correlation. L p and the slope of E p -L p relation present an anti-correlation, which indicates that the causes of spectral variations might be different between luminous and faint sources. E p shows a positive correlation with the black hole mass. We discuss the implications of these results.