Abstract:An efficient and convenient approach for the synthesis of tetrahydrobenzo[b]pyran derivatives under mild condition using the task specific ionic liquid 1,8-diazabicyclo[5.4.0]-undec-7-en-8-ium acetate ([DBU][Ac])as an efficient catalyst is described. A wide range of aromatic aldehydes easily undergo condensation with malononitrile and 5,5-dimethylcyclohexane-1,3-dione (dimedone) to afford the desired products in excellent yields. Taking into account the environmental and economical considerations, the present … Show more
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