“…50 Furthermore, there is evidence presented that the diastereoisomers interconvert under basic conditions due to the resonance effect observed for the deprotonated species. 39,46,51 Eventually, the verification of the aforementioned interconversion rate under ambient conditions could be achievable with dynamic high-performance liquid chromatography (DHPLC). 52…”
Four tris(salicylideneanilines) (TSANs) with gradually increased steric interactions between keto-enamine moiety and neighbouring phenyl substituent are presented. The steric interactions are induced by placing two alkyl groups in ortho position...
“…50 Furthermore, there is evidence presented that the diastereoisomers interconvert under basic conditions due to the resonance effect observed for the deprotonated species. 39,46,51 Eventually, the verification of the aforementioned interconversion rate under ambient conditions could be achievable with dynamic high-performance liquid chromatography (DHPLC). 52…”
Four tris(salicylideneanilines) (TSANs) with gradually increased steric interactions between keto-enamine moiety and neighbouring phenyl substituent are presented. The steric interactions are induced by placing two alkyl groups in ortho position...
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