Base-free transfer hydrogenation of aldehydes and ketones catalyzed by imidazolin-2-iminato actinide complexes

Eisen, Moris S.; Deka, Hemanta; Fridman, Natalia; Koneczny, Marvin; Tamm, Matthias

doi:10.1039/d2cy01362b

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2024

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Cited by 4 publications

References 59 publications

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Bidentate Ru(II)‐NC Complexes as Catalysts for Transfer Hydrogenation of Ketones with Ethanol

Li,

Lian,

Wang

et al. 2024

Asian J Org Chem

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We developed a bidentate Ru(II)‐NC‐catalyzed transfer hydrogen reaction of ketones using ethanol (EtOH) as the hydrogen source under a weak base condition. The control experiments suggested that the reaction proceeds via the Ru‐H mechanism and yields ethyl acetate as the only byproduct. The deuterium‐labeling experiments further showed that hydrogen evolved from the CH2 and OH groups. The results provide a new weak base system for the transfer hydrogen reaction of ketones using ethanol as the hydrogen donor.

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Bidentate Ru(II)‐NC Complexes as Catalysts for Transfer Hydrogenation of Ketones with Ethanol

Li,

Lian,

Wang

et al. 2024

Asian J Org Chem

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Ethanol as hydrogen donor: An efficient transfer hydrogenation of aldehydes, ketones, and nitroarenes with H-bonded Ru(II)-N-heterocyclic iminium complex

Revathi,

Ghatak

2024

Journal of Catalysis

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Ethanol as Hydrogen Donor: An Efficient Transfer Hydrogenation of Aldehydes, Ketones, and Nitroarenes with H-Bonded Ru(Ii)-N-Heterocyclic Iminium Complex

Ghatak

Revathi

2023

Preprint

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Base-free transfer hydrogenation of aldehydes and ketones catalyzed by imidazolin-2-iminato actinide complexes

Abstract: A series of thorium(IV) (3, 4, 9, 10) and U(IV) (5, 6, 11, 12) complexes decorated with the unsymmetrical imidazolin-2-iminato ligands L1 and L2 were synthesized and found to be...

Cited by 4 publications

References 59 publications

Bidentate Ru(II)‐NC Complexes as Catalysts for Transfer Hydrogenation of Ketones with Ethanol

Bidentate Ru(II)‐NC Complexes as Catalysts for Transfer Hydrogenation of Ketones with Ethanol

Ethanol as hydrogen donor: An efficient transfer hydrogenation of aldehydes, ketones, and nitroarenes with H-bonded Ru(II)-N-heterocyclic iminium complex

Ethanol as Hydrogen Donor: An Efficient Transfer Hydrogenation of Aldehydes, Ketones, and Nitroarenes with H-Bonded Ru(Ii)-N-Heterocyclic Iminium Complex

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