A method has been developed for obtaining 3-alkyl(phenyl)-4(5)-chloro-1- (2,4-dinitrophenyl)pyrazoles from appropriate dinitrophenylhydrazones of 1-chloro-, 1,2-, and 2,2-dichlorovinyl ketones by heating the latter in polyphosphoric acid. The structure of the pyrazoles was studied by IR and 1 H NMR spectroscopy. pyrazoles are promising for making medicinal preparations, dyestuffs, insecticides, insectoacaricides, etc. [1-8], and are formed in reactions of the corresponding 1,2-dichloro-and 2,2-dihalovinyl ketones with alkylhydrazines in the presence of base [9][10][11][12]. An extensive series of 3-alkyl-1-methylpyrazoles and 5-chloro(bromo)-1-methylpyrazoles was obtained by us using new one-stage selective heterocyclization reactions of 2-chloro-and 2,2-dichloro(bromo)vinyl ketones with unsymmetrical dimethylhydrazine [13][14][15].It proved to be possible to synthesize 4(5)-chloro-1-phenylpyrazoles or 1-phenylpyrazoles unsubstituted in positions 4 and 5 by the intramolecular heterocyclization of previously obtained phenylhydrazones of 1-chlorovinylalkyl(aryl)-and 2,2-dichlorovinyl phenyl ketones [9,16]. At the same time, only in the one example of 5-chloro-1-(2,4-dinitrophenyl)-3-phenylpyrazole [17] has the preparation been reported of 1-nitrophenyl-substituted halopyrazoles by the thermal cyclization of the corresponding arylhydrazones of 2,2-dichlorovinyl phenyl ketone. It was shown simultaneously that 2,4-dinitrophenylhydrazones (DNPH) of aliphatic 2,2-dichlorovinyl ketones are not cyclized on thermolysis into the corresponding 5-chloropyrazoles. In a systematic study of the structure of DNPH of dichlorovinyl ketones [17,18] the determining role of the configuration of the hydrazone was established unequivocally. The DNPH of aliphatic ketones exist preferably in the s-cis-anti form, but the DNPH of aromatic ketones exist in the s-trans-syn form, capable of achieving intramolecular heterocyclization. The energy barrier for the transition of one form into the other is fairly high [17], but as was established in [18] the process of syn-anti conversion of geometric isomers of DNPH is catalyzed by acids.In view of the above we have developed a convenient method of obtaining 1-(2,4-dinitrophenyl)-pyrazoles by the thermal heterocyclization of the corresponding 2,4-dinitrophenylhydrazones of 2-chlorovinyl, 1,2-, and 2,2-dichlorovinyl ketones, and of 2,2-dichloroacrolein in an acidic medium. We have established that __________________________________________________________________________________________ A. E.