Band strengths of fundamentals and overtones of the CF and CH chromophores in CHD2F

Kormann, Claudius; Lewerenz, Marius; Qüack, Martin

doi:10.1016/0009-2614(88)85119-4

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The Influence Of Molecular Symmetry and Structure On Anharmo1

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Cited by 12 publications

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“…This is beautifully borne out by ex periment (222,223). The spectra in the molecules CHXY 2 with X, Y = CI, CF3, F, D have been analyzed with a model similar to the one for CHX3 (but more complex) and algorithms developed by the Zurich group (223) in several publications (208, [222][223][224][225]. The order of magnitude of the couplings is similar to the one shown in Table 1 for symmetric tops, with Fermi resonance constants of the order of up to 100 em -I and a number of further couplings.…”

Section: The Influence Of Molecular Symmetry and Structure On Anharmomentioning

confidence: 99%