The photovoltaic spectral features and the behaviors of photocurrent versus the electrode potential for near surface In 0.15 Ga 0.85 As/GaAs quantum well electrodes have been investigated in nonaqueous solutions of ferrocene and acetylferrocene. The photovoltaic spectrum shows a sharp structure that reflects confined stateto-state exciton transition in the quantum well. Deep dips are observed in the photocurrent versus the electrode potential curves in both electrolytes at the different electrode potentials under the illumination of exciton resonance wavelength. These dips are qualitatively explained by considering the interfacial tunneling transfer of photogenerated electron within the quantum well.
IntroductionQuantum wells (QWs) and superlattices (SLs) have drawn much attention in semiconductor physics research and semiconductor-based device development due to their unusual physical properties arising from the energy quantizations and engineered electronic structures. 1,2 A multiple quantum well (MQW) semiconductor used in a solar cell has proved to be in possession of higher conversion efficiency than a bulk semiconductor in the lattice-matched GaAs/(AlGa)As system. 3-6 Nozik et al. first introduced the superlattice and quantum well electrodes as new kinds of semiconductor photoelectrodes into photoelectrochemical studies. 7-13 They studied the quantum confined effect of photoelectrodes and hot electron transfer at a p-doped strained layer or lattice-matched SLs/electrolyte interface, which can dramatically improve the conversion efficiency of the semiconductor photovoltaic cell. 14 Recently, using the tailored band structure of QW, the thermodynamic and dynamic characteristics at the surface of QW electrodes were extensively investigated. Diol et al. pointed out that the electron transfer at the semiconductor/outer-sphere acceptor interface is in the adiabatic coupling regime through a study of a GaAs surface quantum well. 15 Liu et al. used a near surface Al x Ga 1-x As/GaAs quantum well as a probe to study the interfacial electric field distribution, the interaction between the surface states and adsorbates, and the quantum-confined Stark effects induced by surface interaction. [16][17][18][19][20] In this work, we have studied the photocurrent characteristics of strained In x Ga 1-x As/ GaAs QW electrodes in contact with nonaqueous electrolytes in order to understand the interfacial behavior of the photogenerated carriers confined in quantum well. Deep dips in the photocurrent vs potential curves were found in our experiments, indicating the existence of tunneling interfacial transfer of photogenerated electrons.