Abstract:Nitrogen‐Nitrogen (N–N) bond‐containing functional groups in natural products and synthetic drugs play significant roles in exerting biological activities. The mechanisms of N–N bond formation in natural organic molecules have garnered increasing attention over the decades. Recent advances have illuminated various enzymatic and nonenzymatic strategies, and our understanding of natural N–N bond construction is rapidly expanding. A group of didomain proteins with zinc‐binding cupin/methionyl‐tRNA synthetase (Met… Show more
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