“…[2] To carry forward its advantages while overcoming the weaknesses, great attention has been poured into the wood-like materials based on a variety of fireresistant building blocks and the scalable bottom-up methods. [3] The wood-like aligned channel structure with a diameter of dozens of micrometers endows those materials with unique anisotropic mechanical and thermal properties, which results in their promising performance in applications such as mechanical support, [1f, 4] acoustic insulation, [5] water purification, [6] and heat insulation. [1f, 3a, 7] In recent years, based on the understanding of the wood structure, various wood-like materials with unique physical properties and wide applications have been developed, among which aerogels with excellent thermal insulation are one of the most important research topics.…”