BaB2O4-NaBO2-NaF-NaCl system for beta BBO single crystal growth

Nikolov, V.; Koseva, I.; Kuvandjiev, N.

doi:10.1016/j.jcrysgro.2021.126474

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2022

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“…In the case of dealing with complex fluxes, significant resources are spent at the research stage devoted to searching for the desirable phase and studying mechanisms occurring in the flux system. [8][9][10] To obtain the stoichiometric composition, it is necessary to provide a detailed study of the solubility of individual components of the crystal-forming compounds (including its thermal dependence); the partition coefficients of different components can have a huge difference, leading to the inconsistency of the actual composition with the one determined by the flux and to a change in the physical and chemical properties of the grown crystals. 11 The construction of the phase diagram of systems with a complex solvent and soluble substance is an almost unsolvable problem.…”

Section: Introductionmentioning

confidence: 99%