Rate Equation for Adsorption of a Neutral Substance at a Metal-Electrolyte Interface

EChem++ – An object-oriented problem solving environment for electrochemistry. Part 5. A differential-algebraic approach to the error control of adaptive algorithms

“…Within the electrochemical literature it has been often assumed that adsorption proceeds sufficiently fast that equilibrium forms of the adsorption isotherms may be employed [3][4][5][6][7][8][9][10][11][12][13][14][15][16][17]. Dynamic (rate controlled) adsorption processes, however, were considered only either conceptionally [18][19][20] 1 or for specific mechanisms [22][23][24]. A model that treats two dynamic adsorption steps coupled to a heterogeneous electron transfer of the adsorbed species has been recently described by Chevallier et al [24].…”

Phase Transitions in Two‐dimensional Adlayers at Electrode Surfaces: Thermodynamics, Kinetics, and Structural Aspects

“…Adsorption control The kinetics of the adsorption step in the absence of mass transport control was treated by Lorenz [87] and Delahay [89,90] assuming either a Langmuir-or a Temkin-type formalism.…”

Kinetic study of bromide adsorption on Hg by a combined equivalent-circuit reaction-mechanism modeling of EIS data

“…In order to obtain a comprehensive understanding of this basic phenomenon, many research groups have studied and described its main features [1][2][3][4][5][6][7][8][9][10][11][12][13][14]. Much of our knowledge comes from classical studies in which adsorption takes place within a liquid electrodeelectrolyte interface.…”