B,N-doped PAHs from tridentate ‘Defects’ – a bottom-up convergent approach for π-extended systems

Abstract

A logic construction of monomeric subunits armed with the functionality open for post-synthetic reactivity leads to a convergent formation of pi-extended defected units. The kinetic or thermodynamic control entraps either...

Triangularly shaped cyclic defects for the selective boron doping of π-extended systems

“…optoelectronics, which will require further development of synthetic approaches that, beside the edge modulation of (nano)graphene, will also efficiently lead to internal introduction of boron( iii ) that will blossom in the near future extending the potential for a predictable formation of π-conjugated systems with a controlled doping degree. 49…”