TiO 2 /N-cellulose nanocomposite was successfully prepared in the (cyclohexyl)hexyldimethylammonium acetate-dimethyl sulfoxide solution. The obtained composite was characterized with various techniques like UV-Vis/DR, FTIR/DRS, X-ray diffraction, thermogravimetric analysis, DLS method and BET SSA measurements. TiO 2 /N-cellulose nanocomposite exhibited high UV-Vis light absorption with energy gap shifted to the visible region. Additive of TiO 2 /N photocatalyst to cellulose-IL-DMSO solution leads to obtaining the material with higher thermostability and limited photoactivity.