Az Endrődi Formáció kőzettani és palinológiai vizsgálata a Hódmezővásárhely–I fúrásban (Makói-árok) — őskörnyezeti és diagenezis-történeti értékelés

Abstract

This paper presents the results of a mineralogical, petrographic and palynological study of selected Pannonian calcareous marl and sandstone samples penetrated by the Hódmezővásárhely-I (Hód-I) well, Endrőd Formation (Tótkomlós Member, cores 35 and 40, 5167.0-5183.0 m and 5468.0-5486.0 m, respectively); this formation is part of the Makó Trough of the Pannonian Basin, SE Hungary. The studied sections comprise mixed carbonate-siliciclastic rocks with abundant silt-to sand-sized angular grains such as monocrystalline and polycrystalline quartz, muscovite, biotite, chlorite, carbonate and metamorphic rock fragments. This polymictic and immature clast composition reflects the importance of local provenance, suggesting that intrabasinal structural highs represent additional source areas to the basin. Palynological analysis was carried out on selected core segments of the well in order to provide a biostratigraphic framework and palaeoenvironmental interpretation for the studied interval. In the investigated samples two biozones were distinguished: the Spiniferites bentorii oblongus Zone and the Spiniferites paradoxus Zone. The successive changes of the dinocyst assemblages reflect changes in the distance from the shoreline or the terrestrial input from the margin of the Makó Trough. The older assemblage indicates a more proximal setting in relation to the shoreline and/or a higher terrestrial input; the younger dinocyst assemblage -with a more open-water taxa point in relation to a greater distance from the shoreline -represents an increase in the water level, and/or decreased terrestrial input. The predominance of membranous dinocysts in this assemblage indicates a fluctuation in the lake surface salinity, or possibly a shift to a holoplanktonic lifestyle due to periodical oxygen depletion in the water column. The assemblages of both zones demonstrate their regional distribution throughout the whole Pannonian Basin and therefore they can be used to document regional scale trends in phytoplankton communities, as well as implying the communication of water bodies. The colour and preservation of the palynomorphs suggests significant burial heating and the high maturity of the sedimentary organic matter. In the studied samples a series of paragenetic events have been identified using petrographic methods. Early diagenesis was generally represented by cementation (i.e. of framboidal pyrite and carbonates with variable iron content) and weak mechanical compaction. On the other hand, late diagenesis involved pressure solution (chemical compaction), cementation (late pyrite) and, occasionally, dolomite replacement and mineral transformation (smectite to illite) processes. It is noteworthy that in these two core sections neither significant macroporosity nor microporosity were observed, this being due to pervasive cementation.Keywords: Pannonian, endemic, dinocysts, Spiniferites, diagenesis, paragenetic sequence ÖsszefoglalásMunkánkban a Hódmezővásárhely-I fúrás 35. és 40. magfúrási szakaszaiból (5167,0-5183,0 m, ill...

Cements, Waters, and Scales: An Integrated Study of the Szeged Geothermal Systems (SE Hungary) to Characterize Natural Environmental Conditions of the Thermal Aquifer

“…The polymictic and highly immature clast composition reflects the importance of local provenance (e.g., recycled detritus derived from erosion of intrabasinal basement highs) during the deposition of the Újfalu and Algyő sediments. Some previous studies [32,37] have also shown carbonate (dolomite, limestone) source components in the underlying Upper Miocene formations (Szolnok and Endrőd).…”

“…During the Late Miocene and Early Pliocene, the paleo-Danube and paleo-Tisza Rivers progressively filled it with clastic material sourced by the surrounding mountain chains, creating one of the thickest Neogene nonmarine sedimentary sequences in Europe [28]. The central and deepest (average thickness: 2-3 km, locally up tõ 7 km) depression of the Pannonian Basin is the Great Hungarian Plain, including the studied Szeged area (Figure 2), where the majority of the sediments accumulated [28][29][30]32]. Based on recent calculations [33], the water depth of the lake was more than 1000 m in the deepest subbasins.…”

“…Formation represents the stacked deltaic lobes overlain by alluvial deposits of the Zagyva Formation [28][29][30]32]. According to a most recently published article [33], the significant compaction associated with lateral variations of the Neogene sediment thicknesses has created nontectonic normal fault offsets and folds.…”

“…When pore waters become significantly depleted in dissolved oxygen (<0.5 ml/l), a suboxic geochemical zone (including nitrate, manganese, and iron reduction subzones, successively) prevails. Additionally, in marine/brackish sediments, where the pore waters contain dissolved sulfate and are devoid of dissolved oxygen, bacterial sulfate reduction (BSR) can operate at shallow depths below the water-sediment interface to depths of a few hundred meters [32,45,46]. In the presence of reactive iron (e.g., Fe-bearing detrital minerals: biotite, chlorite; rock fragments), the precipitation of Fe sulfide as early diagenetic cement phase (i.e., framboidal aggregates of pyrite crystals) is a common process.…”

“…In the presence of reactive iron (e.g., Fe-bearing detrital minerals: biotite, chlorite; rock fragments), the precipitation of Fe sulfide as early diagenetic cement phase (i.e., framboidal aggregates of pyrite crystals) is a common process. Additionally, increased pore water alkalinity is recorded from organic-rich deposits influenced by BSR and pyrite formation [32,45]. When pore waters are devoid of dissolved sulfide, excess Fe 2+ can be incorporated into the carbonate lattice, forming ferroan calcite and/or ferroan dolomite/ankerite cement phases [45].…”