Axially coordinated oligomer of ferrocene-based porphyrin with fullerene C60 for spectroscopic and photocurrent studies

Third-order optical nonlinearities of zinc porphyrins accommodated in the cavity of a doughnut-like molybdenum crown cluster

“…At first, people mainly modified the porphyrin ring by changing the metal atom in the center of the ring, adding different donor and acceptor substituents into the ring, [4][5][6] ligating different atoms or functional groups at the porphyrin meso site, [7][8][9] or designing the oligomers or aggregates of porphyrins, [10][11][12] to tune/enhance the NLO properties of porphyrins. Inspired by the development of organic-inorganic hybrids, researchers gradually combined graphene, [13][14][15] ferrocene, [16][17][18] C 60 [19][20][21] and other inorganic materials with porphyrins to form a series of complexes, which are used to improve the NLO performance of the porphyrins. Polyoxometalates (POMs) are a class of compounds that can reversibly accept or lose electrons without changing their structures, 22 and form a class of donor-acceptor hybrids with porphyrins containing a large π-bond, thus as expected improving the NLO performance of porphyrin materials.…”

“…At first, people mainly modified the porphyrin ring by changing the metal atom in the center of the ring, adding different donor and acceptor substituents into the ring, 4–6 ligating different atoms or functional groups at the porphyrin meso site, 7–9 or designing the oligomers or aggregates of porphyrins, 10–12 to tune/enhance the NLO properties of porphyrins. Inspired by the development of organic–inorganic hybrids, researchers gradually combined graphene, 13–15 ferrocene, 16–18 C 60 19–21 and other inorganic materials with porphyrins to form a series of complexes, which are used to improve the NLO performance of the porphyrins.…”

Synthesis of ferrocene‐based esters by alkylation of carboxylate ions and investigation of their electrochemical and optical behaviors

“…[1][2][3] It has been ascertained that ferrocene-based organic materials could be hired in a wide range of electrochemical applications like supercapacitors, [4][5][6] solar cells, and fuel cells. [2,[7][8][9][10][11] Moreover, their indirect applications in drug delivery and medical approaches have been demonstrated. [12][13][14] The catalytic activity of ferrocene-based materials is broadly discussed in state-of-the-art.…”