In
this study, we show a simple two-step surface engineering method
that uses chemical oxidation (using KOH and NaClO in 1:2 M ratio)-assisted
leaching of metals (Cr, Mn, and Ni) from the surface and an electrochemical
potentiostatic activation enabled resurfacing of only catalytically
active Ni and Mn of the alloy. Such surface-engineered stainless steel
304 (SS-304-Ox-ECA) foils rich in Ni(OH)2 and multivalent
Mn oxides were found to have a coarse texture with uniform nanostructures.
As a result of leached Cr, resurfaced catalytically active sites improved
roughness with nanotexturing and enhanced the charge-transfer ability.
The SS-304-Ox-ECA foil has become a high-performance HER electrocatalyst
that delivered 400 mA cm–2 higher current density
at −0.8 V versus RHE and demanded 210 mV lower overpotential
for a current density of 100 mA cm–2 than pristine
SS-304 foils in 1.0 M KOH. A smaller Tafel slope (90 mV dec–1) and a higher double-layer capacitance (2C
dl = 0.784 μF cm–2) further justified
that the activity enhancement is also due to the improved HER kinetics
and increased electrochemical surface area. This catalytic electrode
of high abundance and low cost is a promising candidate for cost-efficient
hydrogen production from water.