Autoxidation of the Enol Form of 1,2-Dimesitoylcyclohexane. A New Route to Epoxy Ketones<sup>1</sup>

Fuson, Reynold C.; Hatchard, William R.; Kottke, Roger Harris; Fedrick, James L.

doi:10.1021/ja01501a051

Cited by 6 publications

(2 citation statements)

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“…608), and found, as with alcohols, that phenol itself yields two products with this epoxide. The proportion of products could be varied by altering the reaction temperature or the medium polarity.…”

Section: Chi-ch-ch -Chi X = H C1mentioning

confidence: 77%

Ethylene Oxides

Rosowsky¹

1964

Chemistry of Heterocyclic Compounds: A Series of Monographs

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Section: Chi-ch-ch -Chi X = H C1mentioning

confidence: 77%

Ethylene Oxides

Rosowsky¹

1964

Chemistry of Heterocyclic Compounds: A Series of Monographs

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“…Under all of our experimental conditions, at -25, -14, room temperature, 38, and at about 90°, with and without solvent, the formation of compound X was invariant, and at no time were compounds VII, VIII, or IX ever in evidence. In summary the evidence for structure X is (1) correct C, , N analysis, (2) correct molecular weight, (3) correct molar refraction, (4) one active hydrogen per mole of compound, (5) the active hydrogen attached to a nitrogen atom as shown in the infrared spectra for (10) Suggestion from Prof. W. E. von Doering.…”

Section: XImentioning

confidence: 99%