With the rapid growth of urban power transmission cable scale, the harmonic pollution in the high-voltage power grid is more transmitted to other power grids of different voltage levels, which makes the harmonic transmission more complicated, increases the harmonic emission level, and makes it difficult to quantitatively analyze and study the allowable value of users’ electrical pollution emission. Therefore, in this paper, by establishing the harmonic conduction model of the urban high-voltage power grid and considering the equivalent circuit of transformer and transmission cable in the urban power grid, the parameters of transmission cable harmonic transfer coefficient and the allowable emission value of power quality pollution of the urban power grid are deduced and quantitatively analyzed. Then the harmonic transmission and mutual influence of urban power network harmonics in power transmission cable are analyzed through examples, which is helpful to determine the allowable value of harmonic pollution emission scientifically and reasonably.