Autocatalytic Acetylation of Crude Glycerol Using Acetic Acid: A Kinetic Model
Federico M. Perez,
Francisco Pompeo,
Gerardo F. Santori
et al.
Abstract:The aim of this work was to develop a kinetic model based on the power law to describe the evolution of glycerol conversion and product distribution in the crude glycerol (G) acetylation reaction with acetic acid (AA) without the use of a catalyst. For this purpose, experimental tests were carried out with analytical glycerol under different reaction conditions (T = 80–160 °C, AA/G = 1–9 molar ratio, t = 0.25–2 h). The results showed the formation of mono- (MAG), di- (DAG) and tri- (TAG) acetylglycerols, liqui… Show more
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