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Sharma, Anmol; Walia, J.P.S.; Brar, BhupinderS; Sethi, Sanjay

doi:10.4103/0019-5413.185624

Cited by 2 publications

(2 citation statements)

References 2 publications

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“…[8,9] The spiro[acenaphthylene-1,2'-pyrrolidine] derivatives exhibit antibacterial activity against Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, and Streptococcus pyogenus strains and antifungal activity versus Candida albicans, Aspergillus niger and Aspergillus clavatus strains. [10] Acenaphthylene exhibits antimicrobial activity against some selected microbes such as S. aureus, B. subtills, E. coli and P. aeruginosa. [11] The 1, 2, 3-triazoles possess wide applications in the pharmaceutical, polymer and material fields and have shown various biological property such as antibacterial, anti-allergic, anti-HIV activity and also functioning as chemotherapeutic agents for numerous diseases.…”

Section: Introductionmentioning

confidence: 99%

Molecular Structure, Spectral, Electronic and Thermodynamic, First‐Order Hyperpolarizability, NBO and Molecular Docking Studies of Novel Acenaphthylene Pyrrolidine Derivative

Malarkodi

Murugavel²,

Ezhilarasi³

et al. 2018

ChemistrySelect

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The compound 3′‐(1‐benzyl‐5‐methyl‐1H‐1,2,3‐triazole‐4‐carbonyl)‐1′‐methyl‐4′‐(3‐nitrophenyl)‐2H‐spiro[acenaphthylene‐1,2′‐pyrrolidin]‐2‐one [BTNANP] was synthesized and characterized by (FT‐IR/FT‐Raman), NMR (1H and 13C), UV‐Visible, Fluorescence and XRD studies. The molecular geometry was optimized using density functional theory (DFT/B3LYP) method with 6–311G (d,p) basis set in the ground state and compared with the experimental data. The entire vibrational assignments of wave numbers were made on the basis of potential energy distribution (PED) by VEDA 4 programme. Stability of the molecule arising from hyper conjugative interactions, charge delocalization has been analysed using the Natural Bond Orbital (NBO) analysis. It was also confirmed by the assignments of UV‐Vis spectrum. The fluorescence spectrum confirms that the title compound is a red‐light emitting material. In addition, NLO, MEP, Mulliken atomic charges, thermodynamic properties, HOMO and LUMO energy gap were theoretically predicted. The global chemical reactivity descriptors were calculated for BTNANP and used to predict their relative stability and reactivity. The antimicrobial activity of the compound was also tested against the selected bacterial and fungal pathogens. The molecular docking studies concede that the title compound may exhibit inhibition activity against topoisomerase II and lanosterol 14 α‐demethylase.

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Section: Introductionmentioning

confidence: 99%

Molecular Structure, Spectral, Electronic and Thermodynamic, First‐Order Hyperpolarizability, NBO and Molecular Docking Studies of Novel Acenaphthylene Pyrrolidine Derivative

Malarkodi

Murugavel²,

Ezhilarasi³

et al. 2018

ChemistrySelect

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“…The obvious reasons of determining nickel by spectrophotometric method is due to its experimental simplicity, rapidity and the wide applicability of the procedure. Many different organic compounds have been used as spectrophotometric reagents for the determination of nickel (II) in aqueous solutions [1][2][3][4][5]. Addition of some surfactants and protective colloids to nickel (II) complexes have been used to enhance their spectral intensity [6,7].…”

Section: Introductionmentioning

confidence: 99%

Determination of Nickel (II) by Spectrophotometry in Micellar Media

Muthuselvi¹

2017

Pharm Anal Chem

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A spectrophotometry method for the determination of nickel (II) with nicotinohydroxamic acid (NHA) in the presence of Triton X-100 was studied at pH 9.0 using phosphate-borax buffer medium. Molar absorptivity of the sensitized complex was 1.37 × 10 4 L mol -1 cm -1 at 530 nm and adhered to Beer's law in the concentration range 0.43-8.56 μg mL -1 of nickel (II). The molar composition of the sensitized complex was 1:2 (nickel-NHA). The possible interfering effects of various ions were studied. The method was used for the determination of nickel in tap water and alloy samples.

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Cited by 2 publications

References 2 publications

Molecular Structure, Spectral, Electronic and Thermodynamic, First‐Order Hyperpolarizability, NBO and Molecular Docking Studies of Novel Acenaphthylene Pyrrolidine Derivative

Molecular Structure, Spectral, Electronic and Thermodynamic, First‐Order Hyperpolarizability, NBO and Molecular Docking Studies of Novel Acenaphthylene Pyrrolidine Derivative

Determination of Nickel (II) by Spectrophotometry in Micellar Media

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