2007
DOI: 10.1002/anie.200604760
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Au34: A Chiral Gold Cluster?

Abstract: Size-selected, ligand-free gold clusters with diameters less than 2 nm can be routinely generated in the gas phase. The pronounced size dependence of their physical and chemical properties is one of their most important features. Surfacedeposited gold clusters are particularly interesting for applications in nanotechnology and heterogeneous catalysis. [1][2][3][4][5][6][7] One prerequisite for such applications is a detailed knowledge of the cluster structures.The extensive literature on theoretical studies of… Show more

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Cited by 143 publications
(146 citation statements)
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“…The basin found is represented in Fig. 12 (Cartesian Coordinates available as Auxiliary Material [69]) and is consistent with the minimum energy structures already described for the anion Au 34 − [38,82].…”
Section: Au 34supporting
confidence: 84%
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“…The basin found is represented in Fig. 12 (Cartesian Coordinates available as Auxiliary Material [69]) and is consistent with the minimum energy structures already described for the anion Au 34 − [38,82].…”
Section: Au 34supporting
confidence: 84%
“…Also this topology is cage-like as the previous one, but it loses symmetry and drops to point group C 1 being therefore chiral. Chirality seems a frequently occurring phenomenon for gold clusters and has been observed by several researchers [82][83][84][85][86][87][88][89][90]. (Table I).…”
Section: Au 12mentioning
confidence: 66%
“…[2][3][4][5][6][7][8][9][10] Moreover, comparison with experimental data such as a photoelectron spectrum of anionic clusters is a key step to determine the structures of the most stable clusters. For medium-sized thiolate-protected gold clusters, the generation of low-lying structures from DFT calculations is computationally very expensive.…”
Section: Information Required For Predicting the Structure Of A Complmentioning
confidence: 99%
“…The cluster has a HOMO-LUMO gap of 2.40 eV and is thought to be a more realistic model compared to Au 8 (SR) 6 due to the halfunprotected core. In their subsequent study of effects of the length of staple motifs on the stabilization of the smaller thiolate-protected gold clusters, Jiang et al presented a new tetrahedron Au 4 -core-based cluster, Au 10 (SR) 8 . 102 In this new cluster, the tetrahedron Au 4 -core is wrapped by two extended trimeric staple motifs ([Au 3 (SR) 4 ]).…”
Section: Structural Models Formentioning
confidence: 99%
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