Au(111)-supported Platinum Nanoparticles: Ripening and Activity

Abstract

The recent spotlight on supported nanoparticles (NPs) has attracted attention in the field of catalysis and fuel cell technology. Supported NPs can be used as model catalysts to gain a fundamental understanding of the catalytic properties at the interface. Here, especially the wet-chemical preparation of platinum NPs in alkaline ethylene glycol is a powerful approach to synthesize stable particles with a narrow size distribution in the nanometer regime. We combine high resolution imaging by scanning tunneling microscopy with electrochemical characterization by cyclic voltammetry to gain insights into the underlying degradation mechanism of supported platinum NPs, paving the way toward a rational design of supported catalysts with controlled activity and stability.

Probing Semiconductor Properties with Optical Scanning Tunneling Microscopy

“…165,166 Electrochemical STM was successfully employed to study photoelectrochemical reactions in aqueous as well as in ionic liquid electrolytes. [167][168][169][170] However, the full potential of this technique has not been reached. Up to now, only a few reports are published that show the successful characterization of the e.g., in situ water splitting reaction.…”