Atomic Structure and Bonding of Epitaxial CU Films on (1120) A-Al203

Abstract

<jats:p>Thin Cu films were grown on single crystalline <jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" mime-subtype="png" mimetype="image" xlink:href="S1431927600033407_inline1.png" /> α-Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> by molecular beam epitaxy at a substrate temperature of T = 800°C. The nominally 100 nm thin film consists of islands, which have diameters of 0.5-1 μm. High-resolution transmission electron microscopy (HRTEM) and electron energy-loss spectroscopy (EELS) were applied to obtain information about the atomic and electronic structure of the interface. HRTEM studies were performed on the Jeol JEM ARM 1250 operated at 1250 kV (point resolution of 0.12 nm). Analytical studies were conducted on a dedicated scanning TEM (VG HB 501) operated at 100 kV and equipped with a parallel EELS (Gatan 666).</jats:p><jats:p>HRTEM of the Cu/<jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" mime-subtype="png" mimetype="image" xlink:href="S1431927600033407_inline1.png" /> Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>-interface shows an atomically abrupt interface and reveals an epitaxial orientation relationship (1120)<jats:sub>s</jats:sub>[0001]<jats:sub>s</jats:sub> || (111)<jats:sub>Cu</jats:sub> &lt;211&gt;<jats:sub>Cu</jats:sub> (S denotes sapphire) (FIG.l). Close-packed planes and directions in both crystals are parallel to each other resulting in misfits of 2% and 7% in &lt;211&gt;<jats:sub>Cu</jats:sub>- and &lt;110&gt;<jats:sub>Cu</jats:sub>-directions, respectively. The interface is not coherent, but in both directions no misfit dislocations are detectable.</jats:p>