The hyperfine structure of the ground states in a number of positronium hydrides (TPs, DPs, 1 HPs) and MuPs (µ + e − 2 e + ) is determined with the use of highly accurate variational wave functions.We also evaluate the probabilities of various processes in the MuPs system, including the (e − , e + )-pair annihilation and its conversion into the charge conjugate system µ + e − 2 e + → µ − e − e + 2 . * Electronic address: afrolov@uwo.ca