Abstract. Radiative Electron Capture (REC) in collisions of hydrogenic germanium ions with hydrogen is measured for projectile energies between 4 and 12 MeV/u. Extrapolating the resulting centroid energies of the K-REC radiation to zero collision velocity the K-binding energy in helium-like germanium-ions is determined. The value compares well with the theoretical prediction. REC in atomic collisions is advertised as a spectroscopic tool for structure investigations of very heavy few-electron projectiles. PACS" 32.30.Rj; 34.70.+e With the advent of the new generation of heavy-ion accelerators, in particular storage ring facilities, a precise determination of the spectroscopic structure of heavy few-electron ions seems to be feasible even for the heaviest species. This is one of the very challenging aspects in accelerator based atomic physics [1]. Various methods for precision spectroscopy have been proposed and applied, for a survey see e.g. [2]. For spectroscopy with fast beams the Doppler effect is the limiting factor for the accuracy. Hence, several attempts have been made to circumvent this problem. The spectroscopy of slow highly-charged recoil ions [3] is limited both in Z as well as by the presence of spectator electrons; the acceldecel technique [4] seems to be the ultimate solution for precision spectroscopy and has been applied first for S-ions [-5]. However, in-beam calibration (using e.g. Lyman-e/Balmer-fl inter-comparison [6]) or Dopplertuned spectroscopy applying absorber techniques [-7, 8] are also promising methods. All the methods mentioned measure the transition energy between bound states.Radiative Electron Capture (REC) [-9, 10] in contrast gives the transition energy between a free (or a quasi-free) electron in the continuum and a bound state of the ion * Dedicated to Prof. Dr. R Armbruster on the occasion of his 60th birthday [11]. Thus, by knowing the kinetic energy of the electron to be captured with respect to the ion, one can determine the total binding energy for the added electron. Based on this knowledge it is tempting to measure for this purpose REC-radiation from the merged beams region in electron cooler devices [-12]. However, geometry and background radiation do not facilitate this task; additionally the macro and micro structure of the merged beams region have to be known in detail and the Doppler effect could still be a limiting factor for precision measurements. If quasi-free instead of free target electrons (i.e. electrons slightly bound in light target atoms) are used, the width of the REC-transition energy is increased due to the atomic confinement of the electrons, their momentum distribution being characterized by the Compton profile.With a first pilot experiment we will show in this communication that despite the inherent width of the REC-peak in an ion light-atom collision, the centroid of the REC-radiation can be used to determine inner shell binding energies for heavy projectiles with high accuracy.The REC-radiation from hydrogenic Ge 31 ÷ ions, colliding with m...