The nearby extrasolar planet GJ 436b-which has been labelled as a 'hot Neptune'-reveals itself by the dimming of light as it crosses in front of and behind its parent star as seen from Earth. Respectively known as the primary transit and secondary eclipse, the former constrains the planet's radius and mass 1,2 , and the latter constrains the planet's temperature 3,4 and, with measurements at multiple wavelengths, its atmospheric composition. Previous work 5 using transmission spectroscopy failed to detect the 1.4-m water vapour band, leaving the planet's atmospheric composition poorly constrained. Here we report the detection of planetary thermal emission from the dayside of GJ 436b at multiple infrared wavelengths during the secondary eclipse.The best-fit compositional models contain a high CO abundance and a substantial methane (CH 4 ) deficiency relative to thermochemical equilibrium models 6 for the predicted hydrogen-dominated atmosphere 7,8 . Moreover, we report the presence of some H 2 O and traces of CO 2 . Because CH 4 is expected to be the dominant carbonbearing species, disequilibrium processes such as vertical mixing 9 and polymerization of methane 10 into substances such as ethylene may be required to explain the hot Neptune's small CH 4 -to-CO ratio, which is at least 10 5 times smaller than predicted 6 .Using the Spitzer Space Telescope 11 , the Spitzer Exoplanet Target of Opportunity program observed multiple secondary eclipses at wavelengths of 3. 6, 4.5, 5.8, 8.0 Figure 1 shows the observed secondary eclipses with best-fit models, and Table 1 presents the relevant eclipse parameters.The phase of secondary eclipse imposes a tight constraint on the planet"s eccentricity, e, and argument of periapsis, . Using the secondary eclipse times listed in Table 1, in addition to published transit 16 and radial-velocity data 17 , a single-planet Our broadband observations constrain a one-dimensional atmospheric model, using a new temperature and abundance retrieval method 18 . This method searches over a wide parameter space using a functional form for the pressure-temperature profile (based on prior "hot Jupiter" and Solar System studies), a grid of abundance combinations, and energy conservation. We calculated ~10 6 models, which considered both inversion and noninversion temperature profiles and abundances that varied over several orders of magnitude Publisher: NPG; Journal: Nature: Nature; Article Type: Physics letter DOI: 10.1038/nature09013Page 3 of 42per constituent. Figure 2 shows two representative models (the red and blue lines) that fit the data, and and, to a lesser extent, CO, and possibly CO 2 . In a reduced, hydrogen-dominated atmosphere at ~700 K, CH 4 is thermochemically favoured to be the main carbon-bearing molecule. Assuming solar abundances for the elements and the pressure-temperature profile shown in Supplementary Fig. 5, chemical equilibrium predicts 6 a CH 4 -to-H 2 mixing ratio of 7 × 10 4 and an H 2 O mixing ratio of 2 × 10 3 . However, the strong planetary emission at 3.6 m...