2006
DOI: 10.1086/506245
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Atmospheric Chemistry in Giant Planets, Brown Dwarfs, and Low‐Mass Dwarf Stars. II. Sulfur and Phosphorus

Abstract: Thermochemical equilibrium and kinetic calculations are used to model sulfur and phosphorus chemistry in giant planets, brown dwarfs, and extrasolar giant planets (EGPs). The chemical behavior of individual S-and P-bearing gases and condensates is determined as a function of pressure, temperature, and metallicity. The results are independent of particular model atmospheres and, in principle, the equilibrium composition along the pressure-temperature profile of any object can be determined. Hydrogen sulfide (H … Show more

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Cited by 259 publications
(293 citation statements)
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References 61 publications
(97 reference statements)
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“…The 3D simulations described here, as in Showman et al (2009), use 30 wavelength bins (see Showman et al 2009 for more details). For a given metallicity, the chemical mixing ratios and opacities are calculated assuming local chemical equilibrium as a function of local temperature and pressure, accounting properly for depletion of gas-phase species via condensation, follow K. Lodders and collaborators (Lodders 1999;Lodders & Fegley 2002;Lodders 2002;Visscher et al 2006;Lodders 2010). Note, however, that we include only gas-phase opacity; any opacity from clouds/hazes is neglected.…”
Section: Methods: Atmosphere Modelsmentioning
confidence: 99%
“…The 3D simulations described here, as in Showman et al (2009), use 30 wavelength bins (see Showman et al 2009 for more details). For a given metallicity, the chemical mixing ratios and opacities are calculated assuming local chemical equilibrium as a function of local temperature and pressure, accounting properly for depletion of gas-phase species via condensation, follow K. Lodders and collaborators (Lodders 1999;Lodders & Fegley 2002;Lodders 2002;Visscher et al 2006;Lodders 2010). Note, however, that we include only gas-phase opacity; any opacity from clouds/hazes is neglected.…”
Section: Methods: Atmosphere Modelsmentioning
confidence: 99%
“…The code was first developed for Titan's atmosphere ) and since then has been extensively used for the study of giant planets (Marley et al 1996), brown dwarfs (Burrows et al 1997;Marley et al 2002), and hot Jupiters (Fortney et al , 2008Showman et al 2009). We use the opacities described in Freedman et al (2008), including more recent updates (Freedman et al 2014), and the molecular abundances described by Lodders & Fegley (2002) and Visscher et al (2006).…”
Section: Radiative Transfer Modelmentioning
confidence: 99%
“…The methane line lists have been updated using Yurchenko et al (2014), and the alkali line lists have been updated to use the results from Allard et al (2005). Chemical equilibrium grids based on previous thermochemical models (Lodders 1999(Lodders , 2002Lodders & Fegley 2002Visscher et al 2006Visscher et al , 2010Visscher 2012;Moses et al 2013) have been revised and extended to include higher metallicities. These updates will be described in detail in a set of upcoming papers that focus on the new model grid.…”
Section: Atmosphere Modelsmentioning
confidence: 99%