We study the low-energy behavior of the vertex function of a single Anderson impurity away from half-filling for finite magnetic fields, using the Ward identities with careful consideration of the anti-symmetry and analytic properties. The asymptotic form of the vertex function Γ σσ ′ ;σ ′ σ (iω, iω ′ ; iω ′ , iω) is determined up to terms of linear order with respect to the two frequencies ω and ω ′ , as well as the ω 2 contribution for anti-parallel spins σ ′ = σ at ω ′ = 0. From these results, we also obtain a series of the Fermi-liquid relations beyond those of Yamada-Yosida [Prog. Theor. Phys. 54, 316 (1975)]. The ω 2 real part of the self-energy Σ σ (iω) is shown to be expressed in terms of the double derivative ∂ 2 Σ σ (0)/∂ǫ 2 dσ with respect to the impurity energy level ǫ dσ , and agrees with the formula obtained recently by Filippone, Moca, von Delft, and Mora (FMvDM) in the Nozières phenomenological Fermi-liquid theory [Phys. Rev. B 95, 165404 (2017)]. We also calculate the T 2 correction of the self-energy, and find that the real part can be expressed in terms of the three-body correlation function ∂χ ↑↓ /∂ǫ d,−σ , where χ ↑↓ is the static susceptibility between anti-parallel spins. We also provide an alternative derivation of the asymptotic form of the vertex function. Specifically, we calculate the skeleton diagrams for the vertex function Γ σσ;σσ (iω, 0; 0, iω) for parallel spins up to order U 4 in the Coulomb repulsion U . It directly clarifies the fact that the analytic components of order ω vanish as a result of the cancellation of four related Feynman diagrams which are related to each other through the anti-symmetry operation.