Association and Solvation of Silver Nitrate and Perchlorate in Aqueous Ethanol

Гамов, Г. А.; Завалишин, М. Н.; Новиков, И. В.; Dushina, S. V.; Шарнин, В. А.

doi:10.1007/s10953-016-0436-3

Cited by 3 publications

(1 citation statement)

References 34 publications

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“…solvation. The solvation process has been very intensively studied using different methods [ 1 – 9 ].…”

Section: Introductionmentioning

confidence: 99%

Effect of Base–Acid Properties of Mixtures of Ethanol with Water on the Enthalpy of Solution of Cyclic Ethers in these Mixtures at T = 298.15 K

Jóźwiak

2016

J Solution Chem

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The enthalpies of solution of the cyclic ethers 1,4-dioxane, 12-crown-4 and 18-crown-6 in mixtures of ethanol and water have been measured within the whole mole fraction range at T = 298.15 K. The enthalpy of solvation has been calculated. In pure ethanol and pure water, the solvation enthalpy of the investigated cyclic ethers depends linearity on the number of –CH2CH2– groups in the cyclic ether molecules. Based on the analysis of the preferential solvation model proposed by Waghorne, it can be concluded that the 1,4-dioxane, 15C5 and 18C6 molecules are preferentially solvated by water molecules in the range of low water content in these mixtures. The effect of base–acid properties of ethanol–water mixtures on the enthalpy of solution of cyclic ethers in these mixtures has been analyzed. The enthalpy of solution of cyclic ethers correlates with the acidic properties of ethanol–water mixtures in the range of high and medium water content. The results presented are compared with analogous data obtained for the methanol–water and propan-1-ol–water mixtures.

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“…solvation. The solvation process has been very intensively studied using different methods [ 1 – 9 ].…”

Section: Introductionmentioning

confidence: 99%

Effect of Base–Acid Properties of Mixtures of Ethanol with Water on the Enthalpy of Solution of Cyclic Ethers in these Mixtures at T = 298.15 K

Jóźwiak

2016

J Solution Chem

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Loaded Ce-Ag organic-inorganic hybrids and their antibacterial activity

Truffault¹,

Rodrigues

Salgado

et al. 2016

Colloids and Surfaces B: Biointerfaces

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Spectroelectrochemical study of the AMP-Ag⁺and ATP-Ag⁺complexes using silver mesh electrodes

Fato

Zhao

Fodjo

et al. 2018

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In this study, electrochemical reaction mechanism of adenosine monophosphate (AMP) and adenosine triphosphate (ATP) on a silver mesh was investigated in acetate buffer using spectroelectrochemical technique. The results indicate that AMP (or ATP) can form a complex with silver ion originating from a silver mesh when a positive potential was applied. In these complexes, silver ion coordinates with AMP or ATP via their phosphate group. However, when a negative potential was applied, the formed complex disappeared. The complex reaction is therefore an electrochemically reversible process. Further studies using surface-enhancement Raman spectroscopy (SERS) have shown that AMP (or ATP) has a parallel or perpendicular orientation to the silver mesh surface, which is governed by their different binding sites (adenine ring, ribose, and phosphate groups). Herein, the adenine nucleotide-silver mesh surface complexes have displayed a promising biosensing capacity.

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Association and Solvation of Silver Nitrate and Perchlorate in Aqueous Ethanol

Cited by 3 publications

References 34 publications

Effect of Base–Acid Properties of Mixtures of Ethanol with Water on the Enthalpy of Solution of Cyclic Ethers in these Mixtures at T = 298.15 K

Effect of Base–Acid Properties of Mixtures of Ethanol with Water on the Enthalpy of Solution of Cyclic Ethers in these Mixtures at T = 298.15 K

Loaded Ce-Ag organic-inorganic hybrids and their antibacterial activity

Spectroelectrochemical study of the AMP-Ag⁺and ATP-Ag⁺complexes using silver mesh electrodes

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Association and Solvation of Silver Nitrate and Perchlorate in Aqueous Ethanol

Cited by 3 publications

References 34 publications

Effect of Base–Acid Properties of Mixtures of Ethanol with Water on the Enthalpy of Solution of Cyclic Ethers in these Mixtures at T = 298.15 K

Effect of Base–Acid Properties of Mixtures of Ethanol with Water on the Enthalpy of Solution of Cyclic Ethers in these Mixtures at T = 298.15 K

Loaded Ce-Ag organic-inorganic hybrids and their antibacterial activity

Spectroelectrochemical study of the AMP-Ag+and ATP-Ag+complexes using silver mesh electrodes

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Spectroelectrochemical study of the AMP-Ag⁺and ATP-Ag⁺complexes using silver mesh electrodes