Assessment of the Hydrochemical Characteristics and Formation Mechanisms of Groundwater in A Typical Alluvial-Proluvial Plain in China: An Example from Western Yongqing County

Abstract

The geographic location of Yongqing County is optimal, covering the center of the Beijing, Tianjin, and Baoding triangle. However, the economic and social development of Yongqing County in recent years has resulted in negative impacts on groundwater. Therefore, investigating the current status of groundwater chemistry in Yongqing County is of great significance to provide a useful basis for future studies on groundwater quality assessment. The aim of this study is to assess the hydrochemical characteristics and formation mechanisms of the unconfined aquifers of Yongqing County using descriptive statistical and multivariate statistical methods. In addition, ionic ratios, Piper diagram, Gibbs diagrams, and PHREEQC software were used in this study to determine the main factors influencing the hydrochemical characteristics of the unconfined aquifers. The results suggested slightly alkaline groundwater of the unconfined aquifers in the western part of Yongqing County, belonging to the fresh-brackish groundwater type. In addition, the hydrochemistry facies types in the study area are complex, consisting of four facies types, namely HCO3−−Mg·Ca, HCO3−−Na, HCO3−-Na·Ca, and HCO3−-Na·Mg. On the other hand, the main factors influencing the hydrochemical characteristics of groundwater are mineral dissolution followed by some anthropogenic pollution. Rock dominance was the main influencing factor, demonstrated by thedissolution of silicate and carbonate rock minerals. In addition, the alternating adsorption of cations occurring in the aquifer plays a non-negligible effect on the hydrochemical characteristics of the unconfined aquifers in the study area. In fact, the validation results using PHREEQC inverse hydrogeochemical simulations demonstrated consistent conclusions with those mentioned above. According to the findings obtained, the dissolution of carbonate and silicate minerals as well as Na+, K+, and Ca2+ ion exchange in the aquifer are the main factors influencing the hydrochemical characteristics of the unconfined aquifers of Yongqing County. The recommendations suggest put forward in this research are helpful to understand the formation mechanism of hydrochemistry in typical alluvial proluvial plain and provide insights for decision makers to protect the groundwater resources.

Achieving the One Health Goal: Highlighting Groundwater Quality and Public Health

“…Similarly, Li et al [48] also assessed the quality and potential health risks associated with the Linfen basin of the eastern Chinese Loess Plateau, and concluded that F − , Pb, and Cr 6+ were major contaminants responsible for inducing noncarcinogenic health risks in their study area. Bai et al [49] focused on interpreting the hydrochemical characteristics and formation mechanisms of unconfined groundwater in a local area in the North China Plain using multiple approaches. This research could provide significant guidance for further groundwater quality protection and management in overexploited groundwater regions.…”

Distribution and Origins of Hardness in Shallow and Deep Groundwaters of the Hebei Plain, China

“…Recently, Li et al investigated groundwater quality in the Hutuo river alluvial plain of the HBP and showed that about 26% of shallow groundwater and 20% of deep groundwater were characterized by high levels of total hardness (>450 mg/L) [24]. Bai et al investigated groundwater chemistry in Yongqing County in the northern part of the HBP and reported that groundwater total hardness concentration in phreatic aquifers was up to 840 mg/L [25]. Guo et al surveyed groundwater quality in the Bazhou irrigation district of the HBP and found that the total hardness concentration was up to 1483 mg/L in shallow groundwater but less than 90 mg/L in deep groundwater [26].…”