Assessment of intercomponent interaction in phenylene bridged dinuclear ruthenium(ii) and osmium(ii) polypyridyl complexes

Abstract

Assessment of intercomponent interaction in phenylene bridged dinuclear ruthenium(II) and osmium(II) polypyridyl complexes. Dalton Transactions, (23), 3943-3949.

The correlation between magnetism and structures for new solvent free iron(III) and chromium(III) homoleptic 8-quinolinato complexes

“…These methods includes some relativistic effects recommended for metal complexes and has been successfully used for many transition metal complexes [19][20][21][22].…”

Driving the Emission Towards Blue by Controlling the HOMO‐LUMO Energy Gap in BF2‐Functionalized 2‐(Imidazo[1,5‐a]pyridin‐3‐yl)phenols

“…Among our research group, we also focused on a series of organic dyes, namely the imidazo[1,5‐ a ]pyridines, whose biological [27] and photophysical properties [28] have been largely studied and reported in the literature, the latter including large Stokes shifts and high quantum yields. [ 29 , 30 ] Furthermore, they are known to act as ligands in the synthesis of luminescent transition‐metal coordination compounds,[ 31 , 32 , 33 , 34 , 35 ] or in the fabrication of OLEDs. [ 36 , 37 , 38 ] In previous works, the photophysical properties of this class of coordination compounds were investigated on both zinc(II),[ 39 , 40 , 41 ] and silver(I), [42] using opportunely derivatized imidazo[1,5‐ a ]pyridine ligands.…”

Tuning the Fluorescence Emission and HOMO‐LUMO Band Gap in Homoleptic Zinc(II) Complexes with N,O‐Bidentate (Imidazo[1,5‐a]pyrid‐3‐yl)phenols

“…Among nitrogen‐based ligands, imidazo‐pyridines are known for their interesting photochemical properties, both as free molecules and when coordinated to transition metals . In our ongoing study on complexes with nitrogen‐containing ligands, we also investigated zinc(II), and silver(I) complexes bearing N , N ‐coordinated imidazo‐pyridines.…”