Asphaltene Adsorption on Solid Surfaces Investigated Using Quartz Crystal Microbalance with Dissipation under Flow Conditions

Abstract

Asphaltenes can cause operational challenges in petroleum production facilities and adversely affect production by adsorption on mineral surfaces and alteration of the oil wettability of reservoirs. Therefore, understanding asphaltene adsorption mechanisms and their effects is crucial to improving the efficiency of oil production and reducing costs. In this study, we focus on understanding the impact of asphaltene concentration and the depositing environment of asphaltene adsorption on solid surfaces using the quartz crystal microbalance with dissipation (QCM-D) technique. The initial and long-term kinetics of adsorption at different concentrations were examined on three different solid surfaces including silicon dioxide to represent quartz mineral, stainless steel, and gold. The frequency−dissipation data showed evidence of monolayer adsorption initially, followed by multilayer formation. At short times, the adsorbed mass increased linearly with time, suggesting that the process was kinetically controlled rather than diffusion-controlled. The results were reproducible and did not depend on convection velocity but did depend on the surface material. At later stages, the monolayer development appeared to follow the random sequential adsorption (RSA) theory. Once multilayer adsorption commenced, the rates agreed well with the two-layer model of Zhu and Gu, 1990. The impact of asphaltene adsorption on the wettability of the surface was examined using contact angle studies, which showed decreasing water wettability with an increase in the adsorbed mass. The contact angle of water after 12 h of adsorption leveled off at around 100°on all three surfaces. Contact angle measurements were also used to evaluate if brine salinity causes the wettability alteration of surfaces with the adsorbed asphaltene. The results indicate that at 3% NaCl solution, the contact angle decreased only slightly by less than 2°.