The work is devoted to the urgent issues of processing of sulfur-containing and ash-and-slag waste of industrial enterprises. The process flow scheme for obtaining of protective coatings on cement concrete, by impregnation in sulfur melt with high strength, performance properties, and resistance to aggressive environments, was developed. The technological parameters of the process were determined. The addition of ash and slag to the cement concrete allows not only to utilize the waste of heat power industry, but also to increase the strength of the material. Moreover, the applied technology of impregnation provides low thermal conductivity of concrete, and good thermalinsulation characteristics of the material. The increase in strength of samples, containing ash and slag waste, is due to the high dispersion and active surface of ash and slag. The influence of aluminum chloride, an electrophilic agent, on the properties of sulfur binder, was considered. It was shown, that the introduction of aluminum chloride contributed to a more effective protective coating, which provided the samples of cement concrete with high strength, density, and water resistance. The use of an electrophilic agent made it possible to intensify the process of obtaining of inorganic sulfides and composite materials, based on them. It was found, that the application of an electrophilic additive -aluminum chloride -significantly reduced the viscosity of sulfur melt, that was due to the formation of short-chain sulfur radicals. Such a sulfur melt has a fairly high penetrating ability, that provides the formation of a high-quality protective coating.