Arylamine Synthesis Enabled by a Photocatalytic Skeletal-Rearrangement Dehydrogenative Aromatization Strategy
Wei Shu,
Yu-Feng Ren,
Xiao-Yi Chen
et al.
Abstract:Construction of aromatic compounds from non-aromatic compounds with skeletal edit are appealing yet challenging in organic chemistry. Herein, we report an approach for the synthesis of site-selective substituted arylamines via photocatalyzed C-N coupling/skeletal expansion/dehydrogenative aromatization reaction. A wide variety of primary amines, cyclic and acyclic secondary amines as well as iodomethyl cyclopentanones with diverse substitution patterns are suitable for this strategy, providing an unprecedented… Show more
Set email alert for when this publication receives citations?
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.