Abstract. The ionization of the oxonium ions of phenol, anisole, 4-chloro-and 4-methyl-phenol and 4-bromo-, 4-fluoro-and 4-methyl-anisole in concentrated aqueous sulfuric acid has been investigated using UV spectroscopy at 25°C. The sulfuric acid concentrations at half-ionization are within the range 75.2 to 81.8% H,S04, corresponding with pK,'s between -5.87 and -6.52 based on the Hoa acidity function. The substituent effects on the ionization of PhO+H2 and PhO'HMe are small, the Hummet p values being 0.5 kO.1 and 0.9kO.1, respectively.