(Arene)tricarbonylchromium(0) complexes in the synthesis of metal-containing polymers based on vinyl monomers

The polymerization of methyl methacrylate and butyl acrylate initiated by azo-bis-isobutyronitrile in the presence of metal-containing monomers (p-methylstyrene-, stilbene-and α-methylstyrenechromiumtricarbonyl) was studied. Kinetic parameters (i.e. the decrease in the autoacceleration during the polymerization of acrylic monomers, its shift towards a high conversion region in the presence of α-methylstyrenechromiumtricarbonyl, a linear dependence of the molecular weight of a polymethyl methacrylate and the shift of molecular-weight distribution curves to a high molecular weight region with conversion) demonstrate the influence of vinylarenetricarbonyl complexes of chromium on basic steps of polymerization. It is important to note that the above organometallic compounds enable the controlled synthesis of polymers under temperature conditions (50-70 • C) corresponding to those of the industrial polymer production.

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Arenetricarbonylchromium Complexes in Polymerization Transformations by Radical Initiation of Vinyl Polymerization

Семенычева

Artemov

Valetova

et al. 2016

J Inorg Organomet Polym

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(Arene)tricarbonylchromium(0) complexes in the synthesis of metal-containing polymers based on vinyl monomers

Cited by 4 publications

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Polymerization of Metal‐Containing Monomers (MCMs) as a Method for Incorporating Metals in Macromolecules

Polymerization of Metal‐Containing Monomers (MCMs) as a Method for Incorporating Metals in Macromolecules

Vinylarenetricarbonyl complexes of chromium as chain propagation regulators for polymerization of acrylic monomers

Arenetricarbonylchromium Complexes in Polymerization Transformations by Radical Initiation of Vinyl Polymerization

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