Aims. This work is part of a joint observational program aiming to get photometric and spectroscopic information on southern pairs of galaxies. We present optical long-slit spectroscopic data on 80 probable components of pairs, 61 of them collected with a spectral resolution of 3.4 Å, and 19 with 12 Å. Nevertheless, our analysis takes into account 53 components of pairs with better spectral resolution, as 8 of these target galaxies actually belong to optical pairs. For the sample with better resolution, the covered wavelength range is 5724 ≤ λ ≤ 7036 Å. The spectroscopic and photometric information is gathered for an analysis relating galaxy morphologies to their spectra. Methods. We use H α + [N II ] and H α equivalent widths as star formation tracers for the central region of our sample galaxies, and we classify the spectra according to the emission lines' relative strength by looking at their behavior. Results. Some of our sample galaxies exhibit high central star formation, most of them belonging to close pairs. However, not all galaxies' components of close pairs show this behavior. This may be a clue that besides interaction, other agents can stimulate central emission in binary galaxies. We suggest an enhancement in the number of galaxies with peculiar spectra (probably Seyferts) in our binary sample, when compared to isolated galaxies. Our data indicates that the morphological types of interacting galaxies are related to their spectral characteristics, as almost all early-type galaxies of our sample do not exhibit central optical emission. We note that the star formation activity is most likely to take place in both pairs' components, with a slightly higher mean strength for the less bright component of the pair. It is interesting to point out that most spirals exhibiting a strong HII emission line spectra present either a bar or a peculiarity, but on a general basis we do not find an enhancement of star formation in our interaction sample.