Abstract:Recently, since the demand of rare earth permanent magnet for high temperature applications such as an electric motor has increased, dysprosium (Dy), a heavy rare earth element, is becoming important due to severe bias in its production. To fulfill the increasing need of Dy, recycling offers as a promising alternative. In recycling of rare earths, Hydro-metallurgical extraction method is mainly used however it has adverse environmental effects. Liquid metal extraction on the other hand, is an eco-friendly and … Show more
“…In many industries, great emphasis is placed on introducing better and better materials with specific properties into products. Both materials exhibiting the so-called soft magnetic properties [1,2] and hard magnetic properties [3][4][5] are desirable. Due to the constantly growing progress in the field of electronics and electrical engineering, materials with good magnetic properties that can be used as transformer cores or chokes are of particular interest [5][6][7].…”
Amorphous alloys are characterized by a disordered structure. The arrangement of atoms is chaotic and it is difficult to determine the parameters describing their properties. In soft magnetic ferromagnets, one of the main parameters describing their applicability is the Curie temperature. However, in amorphous materials, due to their metastable nature, the Curie temperature occurs in a rather narrow range. Using the measurements of the magnetic saturation polarization as a function of temperature and the critical exponent β = 0.36, the value of the Curie temperature can be determined. The paper presents the results of µ0M (T ) 1/β tests carried out for two amorphous alloys with similar chemical composition. The influence of chemical composition on the course of the µ0M (T ) curve and changes in the share of characteristic areas describing rearrangements of atoms in the structure of alloys were observed.topics: bulk amorphous alloys, Curie temperature, coercieve field, soft magnetic properties
“…In many industries, great emphasis is placed on introducing better and better materials with specific properties into products. Both materials exhibiting the so-called soft magnetic properties [1,2] and hard magnetic properties [3][4][5] are desirable. Due to the constantly growing progress in the field of electronics and electrical engineering, materials with good magnetic properties that can be used as transformer cores or chokes are of particular interest [5][6][7].…”
Amorphous alloys are characterized by a disordered structure. The arrangement of atoms is chaotic and it is difficult to determine the parameters describing their properties. In soft magnetic ferromagnets, one of the main parameters describing their applicability is the Curie temperature. However, in amorphous materials, due to their metastable nature, the Curie temperature occurs in a rather narrow range. Using the measurements of the magnetic saturation polarization as a function of temperature and the critical exponent β = 0.36, the value of the Curie temperature can be determined. The paper presents the results of µ0M (T ) 1/β tests carried out for two amorphous alloys with similar chemical composition. The influence of chemical composition on the course of the µ0M (T ) curve and changes in the share of characteristic areas describing rearrangements of atoms in the structure of alloys were observed.topics: bulk amorphous alloys, Curie temperature, coercieve field, soft magnetic properties
Liquid metal extraction (LME) for recycling rare-earth elements from magnets is studied, in the present study, to examine its suitability as an environmentally friendly alternative for a circular economy. While Nd (neodymium) extraction efficiency can easily reach almost 100%, based on the high reactivity of Mg (magnesium), Dy (dysprosium) extraction has been limited because of the Dy–Fe intermetallic phase as the main extractive bottleneck. In the present paper, the boro-additive effect is designed thermodynamically and examined in the ternary and quinary systems to improve the selectivity of recovery. Based on the strong chemical affinity between B (boron) and Fe, the effect of excess boron, which is produced by the depletion of B in FeB by Mg, successfully resulted in the formation of Fe2B instead of Dy–Fe bonding. However, the growth of the Fe2B layer, which is the reason for the isolated Mg, leads to the production of other byproducts, rare-earth borides (RB4, R = Nd and Dy), as the side effect. By adjusting the ratio of FeB, the extraction efficiency of Dy over 12 h with FeB addition is improved to 80%, which is almost the same extraction efficiency of the conventional LME process over 24 h.
During the liquid metal extraction reaction between a Nd-Dy-Fe-B magnet and liquid Mg, Nd rapidly diffuses out of the magnet, whereas Dy is not extracted due to the reaction with the matrix and the formation of Dy2Fe17 phase. In addition, theDy2O3 phase exists at the grain boundaries. Until now, only the effect of the Dy2O3 phase on the extraction of Dy has been reported. In this study, the effect of the Dy2Fe17 phase on the extraction of Dy from the Nd-Dy-Fe-B magnet was investigated in liquid Mg. The formation of the Dy2Fe17 phase during the reaction between Mg and matrix (RE2Fe14B) was first examined using a thermodynamical approach and confirmed by microstructural analysis. It was observed that Dy extraction was dominated by Dy2Fe17 phase decomposition from 3 h to 24 h, followed by Dy2O3 phase dominant reaction with Mg. Comparing the activities of the Dy2Fe17 phase and the Dy2O3 phase, the reaction of Dy2Fe17 is dominant, as compared to the Dy2O3 phase. Finally, at 48 h, the high Dy extraction percentage of 93% was achieved. As a result, in was concluded that the Dy2Fe17 phase acts as an obstacle in the extraction of Dy. In the future, if research to control the Dy2Fe17 phase proceeds, it will be of great importance to advance the recycling of Dy.
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